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CAS NO.38721-52-7
Product Name: | Lithium triisobutylhydroborate |
Synonyms: | LITHIUM TRI-S-BUTYLHYDROBORATE;LITHIUM TRI-SEC-BUTYLBOROHYDRIDE;LITHIUM TRI-SEC-BUTYLHYDRIDOBORATE;LITHIUM TRIISOBUTYLHYDROBORATE;L-SELECTRIDE(R);l-selectride solution;(beta-4)-borate(1-hydrotris(1-methylpropyl)-lithium;LITHIUM TRI-SEC-BUTYLBOROHYDRIDE, 1M IN THF |
CAS: | 38721-52-7 |
MF: | C12H28B.Li |
MW: | 190.1 |
EINECS: | 254-101-1 |
Product Categories: | B (Classes of Boron Compounds);Classes of Metal Compounds;Li (Lithium) Compounds;Reduction;Synthetic Organic Chemistry;Tetrahydroborates;Typical Metal Compounds;38721-52-7 |
Mol File: | 38721-52-7.mol |
Uses | Lithium triisobutylhydroborate is used as a reducing agent. Reagent for: Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters. Diastereoselective reduction reactions. Hydride reduction of the Danishefsky pyranones. Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes. Synthesis of alkanols by carbonylation reactions. |
Uses | L-Selectride Solution is a reducing agent which is used in the preparation of oxygen heterocycles. Used also as a reactant in the synthesis of novel bicicyclo[3.1.0]hexane analags which may prove useful in the treatment of depression. |
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