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CAS NO.185812-86-6
Product Name: | PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE |
Synonyms: | DI-BROMOBIS(TRI-T-BUTYLPHOSPHINO)DIPALLADIUM (I);Dibromobis(tri-tert-butylphosphine)dipalladium;Dibromobis(tri-tert-butylphosphine)dipalladium(I); |
CAS: | 185812-86-6 |
MF: | C24H56Br2P2Pd2 |
MW: | 779.31 |
EINECS: | |
Product Categories: | Pd;metal phosphine complex |
Mol File: | 185812-86-6.mol |
Uses | Coupling reactions. Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides. Especially active in difficult aminations.Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) is used as a catalyst for Suzuki coupling, Negishi coupling and Buchwald-hartwig amination reactions. It is used as a catalyst for C-C, C-N and C-S bond formation, gamma-arylation of alfa,beta-unsaturated esters and diastereoselective arylation of 4-substituted cyclohexyl esters. It is also involved in aromatic halide substitution reactions. |
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