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CAS NO.12012-95-2
| Product Name: | Allylpalladium(II) Chloride Dimer |
| Synonyms: | DI-MU-CHLOROBIS[(ETA-ALLYL)PALLADIUM(II)];ALLYLPALLADIUM CHLORIDE DIMER;ALLYLPALLADIUM(II) CHLORIDE DIMER;allylpaladium;allylpaladiumchloridedimer;Bis(pi-allyl)dichlorodipalladium;Bis(pi-allylpalladium chloride);Diallyldichlorodipalladium |
| CAS: | 12012-95-2 |
| MF: | C6H10Cl2Pd2 |
| MW: | 365.89 |
| EINECS: | 234-579-8 |
| Product Categories: | Pd;Alkyl Metals;Catalysts for Organic Synthesis;Classes of Metal Compounds;Grignard Reagents & Alkyl Metals;Homogeneous Catalysts;Metal Complexes;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Homogeneous Pd Catalysts;Palladium;organometallic complexes |
| Mol File: | 12012-95-2.mol |
| Uses | Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry. |
| Uses | [Pd(allyl)Cl]2 can be used as a catalyst: For the silylation of organobromides. To synthesize α-aryl carbonyl compounds by coupling reaction between aldehydes and aryl halides. To prepare various arylthiophene derivatives by cross-coupling reaction with aryl halides via C-H functionalization. Application Guide for Palladium Catalyzed Cross-Coupling Reactions ChemDose: Convenient Dosing of Catalysts and Reagents |
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