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CAS NO.2923-28-6
Product Name: | SILVER TRIFLUOROMETHANESULFONATE |
Synonyms: | SILVER (I) TRIFLUOROMETHANE SULFONATE;SILVER(I) TRIFLUOROMETHANESULPHONATE;SILVER TRIFLATE;SILVER TRIFLUOROMETANESULFONATE;SILVER TRIFLUOROMETHANESULFONATE; |
CAS: | 2923-28-6 |
MF: | CAgF3O3S |
MW: | 256.94 |
EINECS: | 220-882-2 |
Product Categories: | triflate;metal triflate compounds;Ag (Silver) Compounds;Transition Metal Compounds;Ag;OTf&NTf series;Catalysts for Organic Synthesis;Classes of Metal Compounds; |
Chemical Properties | light beige crystalline powder |
Uses | Silver Trifluoromethanesulfonate is used to generate cationic rhodium catalysts from chlororhodium complexes for the hydrophosphination of acetylenes. It is also employed as a catalyst for the preparation of silyl ethers by hydrosilylation of aldehydes. |
General Description | Silver trifluoromethanesulfonate p-complexes of monoenes, dienes, trienes, monoynes and diynes have been prepared. It reacts with 2-fluoro- and 3-fluoro-4-alkoxystilbazoles to afford the mesomorphic complexes. Iodine monochloride/AgOTf constitutes an efficient promoter system for the O-glycoside synthesis. |
Purification Methods | Recrystallise it twice from hot CCl4 [Alo et al. J Chem Soc, Perkin Trans 1 805 1986]. Store it in the dark. [Beilstein 3 IV 34.] |
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